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61.
62.
近年来, 由于钙钛矿材料优良的光学吸收和电荷传导特性, 有机无机杂化固态太阳能电池取得了突破性的进展. 自2009年首次报道了光电转换效率为3.8%的钙钛矿太阳能电池以来, 该类电池的效率不断突破. 基于介孔薄膜的电池已取得了超过16.7%的认证光电转换效率, 基于平板异质结结构电池光电转换效率达到19.3%, 已接近传统硅基太阳能电池的光电转换效率. 本文将介绍有机无机杂化钙钛矿作为光电材料的光学物理结构特性, 以及在固态太阳能电池中的应用. 基于固态钙钛矿太阳能电池结构上的差异, 分别介绍其在多孔结构、平板异质结结构、柔性结构以及无空穴传导材料结构电池工作特性和各自优势, 以及影响电池特性的主要影响因素, 特别是钙钛矿成膜控制等. 并阐述对钙钛矿电池的理解和进一步提高固态钙钛矿电池光电转换效率需要关注的重点以及展望. 相似文献
63.
提出了一种利用半导体环形激光器(SRLs)的新型高速双向、双信道混沌保密通信系统. 在该系统中, 首先利用交叉双光反馈对驱动激光器的顺时针模式和逆时针模式的混沌延时特征进行抑制. 然后将此混沌信号注入到一对响应激光器对应的顺时针模和逆时针模中, 以实现带宽的增强及混沌同步. 最后基于响应激光器之间的混沌同步, 实现高速率、双向、双信道的混沌保密通信. 通过对驱动激光器在交叉双光反馈作用下的混沌特性、以及响应激光器在不同条件下的同步特性进行了相关理论和仿真研究, 结果表明: 驱动激光器在合适的交叉双光反馈作用下可以产生延时特性被良好隐藏的顺时针模式和逆时针模式混沌信号; 在该混沌信号的注入下, 响应激光器输出的混沌信号带宽可以得到明显增强; 通过设置合适注入强度值和频率失谐值, 响应激光器之间可实现高质量的等时混沌同步. 最后, 对系统的双向、双信道混沌保密通信特性进行了讨论. 当10 Gbit/s信号传输距离为10 km时, 解调信息Q因子值仍可保持在6以上. 相似文献
64.
利用T矩阵和离散坐标法研究了取向比对椭球粒子散射特性的影响, 计算了小尺度范围内椭球粒子的散射特征参量, 包括消光效率因子、不对称因子、单次散射反照率、散射相矩阵及双向反射函数(BRDF). 结果表明, 椭球粒子的散射特性与取向比密切相关, 粒子取向比会影响散射参量的振荡频率和振幅, 与球形粒子散射参量的相对差异也呈周期振荡趋势. 研究还发现, 某些特殊粒子尺寸的散射参量与粒子取向比基本无关. 在多次散射条件下, 分析不同取向比粒子群的BRDF随反射角和光学厚度的变化特性. 结果显示: 不同取向比粒子群的BRDF随反射角的变化趋势基本一致, 球形粒子群比非球形粒子群的BRDF曲线波动振幅更大; 球形-非球形粒子的BRDF相对差异随光学厚度和取向比的增大而减小, 随入射角的增大而增大. 相似文献
65.
Nathalie Lavoine Julien Bras Tsuguyuki Saito Akira Isogai 《Macromolecular rapid communications》2016,37(13):1033-1039
Improving thermal stability of TEMPO‐oxidized cellulose nanofibrils (TOCNs) is a major challenge for the development and preparation of new nanocomposites. However, thermal degradation of TOCNs occurs at 220 °C. The present study reports a simple way to improve thermal stability of TOCNs by the heat‐induced conversion of ionic bonds to amide bonds. Coupling amine‐terminated polyethylene glycol to the TOCNs is performed through ionic bond formation. Films are produced from the dispersions by the casting method. Infrared spectroscopy and thermogravimetric analysis confirm conversion of ionic bonds to amide bonds for the modified TOCN samples after heating. As a result, improvement of TOCNs' thermal stability by up to 90 °C is successfully achieved.
66.
将目标物上的某一点在两幅图像上的对应点之间的灰度值和坐标值进行比较,结合惯性导航系统的输出信号,可得到运载体与目标物间的距离。对惯性辅助电光测距方法进行了理论分析、测距仿真及误差分析。仿真结果与真实值之间的误差小于5%,表明了该算法的可行性和整个设计的可用性。 相似文献
67.
D.A. Hall B. Cherdhirunkorn P.J. Withers T. Mori 《Journal of the mechanics and physics of solids》2005,53(2):249-260
This paper presents micromechanics based analysis of elastic strain and changes in the texture of poled polycrystalline ferroelectric PZT ceramics for direct comparison with synchrotron X-ray measurements. The grains are modelled as spherical inclusions, to which transformation strains are assigned depending on the fractions of different ferroelectric domains. Eshelby's inclusion problem with the classical self-consistent method is applied to evaluate the elastic state of the grains. In particular, the elongation due to lattice elastic strain is calculated as a function of inclination Ψ relative to the polar axis. The ratio of diffraction peak intensities, corresponding to the domain fractions, is also expressed as a function of Ψ. This analysis identifies the special character of the reflection, for which the lattice strain along in the stress free state is independent of ferroelectric domain population and hence unaffected by poling. The elongation due to the lattice strain parallel to and peak intensity ratio are expressed in terms of the overall macroscopic strain of a poled specimen, each having a dependence. 相似文献
68.
本文定量分析了"瑞利球"实验的动力学过程。"瑞利球"实验中构建了一个"怪坡",通过对两导轨的控制,使均质圆球看起来像在"爬坡"。文中据刚体运动原理构建了物理模型,并分析系统的受力情况和运动过程,导出了均质圆球"爬坡"的最大高度的公式。在忽略空气阻力与摩擦力情况下,当两导轨杆初始距离远小于圆球半径、小球刚好不能掉落时突然合拢两导轨使其平行、两导轨初始夹角等于两倍导轨倾斜角时,均质圆球可以达到最大高度和最远距离。 相似文献
69.
Theodore Yao-tsu Wu 《Acta Mechanica Sinica》1995,11(4):289-306
The bidirectional long-wave model introduced by Wu (1994)[1] and Yih & Wu (1995)[2] is applied to evaluate interactions between multiple solitary waves progressing in both directions in a uniform channel of
rectangular cross-section and undergoing collisions of two classes, one being head-on and the other overtaking collisions
between these solitons. For a binary head-on collision, the two interacting solitary waves are shown to merge during a phase-locking
period from which they reemerge separated, each asymptotically recovering its own initial identity while both being retarded
in phase from their original pathlines. For a binary overtaking collision between a soliton of height α1 overtaking a weaker one of height α1, the two solition peaks are shown to either pass through each other or remain separated throughout the encounter according
as α1/α2 or <3, respectively. With no phase locking during the overtaking, the two solitary waves re-emerge afterwards with their
initial forms recovered and with the stronger wave being advanced whereas the weaker one retarded in phase from their original
pathlines. By extension, the theory is generalized to apply to uniform channels of arbitrary cross-sectional shape.
The Inaugural Pei-Yuan Chou Memorial Lecture, presented at The Sixth Asian Congress of Fluid Mechanics. Singapore, 21–26 May
1995 相似文献
70.
Tuan Anh Pham 《International journal of quantum chemistry》2019,119(1):e25795
Understanding physicochemical properties of liquid electrolytes is essential for predicting and optimizing device performance for a wide variety of emerging energy technologies, including photoelectrochemical water splitting, supercapacitors, and batteries. In this work, we review recent progress and open challenges in predicting structural, dynamical, and electronic properties of the liquids using first-principles approaches. We briefly summarize the basic concepts of first-principles molecular dynamics (FPMD), and we discuss how FPMD methods have enriched our understanding of a number of liquids, including aqueous solutions, organic electrolytes and ionic liquids. We also discuss technical challenges in extending FPMD simulations to the study of liquid electrolytes in more complex environments, including the interface between electrolytes and electrodes, which is a key component in many energy storage and conversion systems. 相似文献